Rate Laws

We have said before that the rate of a reaction is increased by an increase in the concentration of the reactants. This can be written mathematically in an equation called a rate law.

For a reaction such as 2 A + 3 B --> C + 3 D (clearly made up as a generic example) the rate law has the form:

 

where k is a constant (called the rate constant), [A] is the concentration of A, [B] is the concentration of B, and x and y are integers. It would be convenient if x and y matched the coefficients in the reaction, and they often do, but not always. The only way to determine the values of x, y (and k for that matter) are through experiment.

To understand what this equation says, and what it can do for us we need to know two things. 1. How to calculate x,and y, 2. how to calculate k, and 3. what do those values mean. We’ll take those on one at a time.

About Us | Site Map | Privacy Policy | Contact Us | ©2009 Lawrence McAfoos